The county's police force say they were called at 5.20pm on Tuesday (April 8) to the A19 near Bagby near Thirsk after a crash involving a white Citroen DS and a blue Kia Picanto.
A force spokesman said: "We’re appealing for witnesses and dashcam footage following a serious collision which saw the drivers of both vehicles taken to hospital by road ambulance and air ambulance with significant injuries.
"The road was closed for five hours while we investigated the scene and to allow the vehicles involved to be recovered.
"We’re appealing for any witnesses to the collision, anyone who may have seen the vehicles prior to the collision, or anyone with relevant footage, to contact us.
"Please email ross.moralee@northyorkshire.police.uk if you can help. Alternatively, you can call North Yorkshire Police on 101 and ask for TC 1253 Moralee."
Please quote reference 12250062230 when passing on information.
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